Sirvi Autor "Nuortila, C." järgi
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Kirje Effects of storage on the properties of rapeseed oil and alcohol blends(2021) Nuortila, C.; Heikkilä, S.; Help, R.; Suopanki, H.; Sirviö, K.; Niemi, S.Kinematic viscosity and density are important fuel properties because they influence fuel atomisation during injection into the engine cylinder. The viscosity and density of neat vegetable oils usually are too high to allow optimal use of these oils in compression ignition engines. Blending vegetable oils with alcohols can improve these properties, but it is not known whether the blend properties remain stable during storage. This study measured kinematic viscosity (at 40 °C), density (at 15 °C) and surface tension of rapeseed oil-alcohol blends that had been stored in closed borosilicate glass bottles at room temperature in the dark for 49 weeks. The values were compared with those of the fresh blends. Further measurements of oxidation stability for the rapeseed oil and the blends were taken after 72 weeks of storage. The blends consisted of rapeseed oil with ethanol at 5 vol–%, and rapeseed oil with 1–butanol at 5 vol–%, 10 vol–%, 20 vol–% and 30 vol–%. All in all, the observed changes during storage were small. Density values deviated by less than 1%, surface tension by no more than 3% and kinematic viscosity differed from the fresh blends’ values by 1% to 8%. Surface tension had increased in some blends and decreased in others. Kinematic viscosity rose in all blends, with the smallest increase measured for the rapeseed oil–butanol 30 vol–% blend. This blend also showed the best oxidation stability, which was close to six hours.Kirje Properties of chemically stabilized methanol-HVO blends : [Retracted](Estonian University of Life Sciences, 2024) Wang-Alho, H.; Sirviö, K.; Balogun, F.; Kaivosoja, J.; Nuortila, C.; Mikulski, M.; Niemi, S.Kirje Storage stability of rapeseed methyl ester stored in a sealed barrel for seven years(Estonian University of Life Sciences, 2021) Heikkilä, S.; Sirviö, K.; Nuortila, C.; Niemi, S.Storage stability is one of the main quality parameters related to fatty acid methyl esters (FAME) biofuels. The deterioration of biofuels´ properties during storage is a more serious issue than with conventional fuels. In particular, lengthy storage threatens the oxidative stability of FAME fuels because factors such as the presence of air, elevated temperatures or presence of metals promote the oxidation process. Consequently, the acceptable storage time for FAME fuels is generally regarded to be regrettably short, at no more than six to12 months. However, storage conditions play an important role in determining actual storage stability. This study aimed to investigate and evaluate any deterioration in the quality of rapeseed methyl ester (RME) fuel that has been stored for as long as seven years in adequate storage conditions. The fuel was stored in the dark, contained in a sealed steel barrel in an insulated shipping container outdoors. The temperature of the container varied with seasonal fluctuation, but the fuel never froze during storage. The study analysed six key fuel properties of the RME: ester content; water content; density; kinematic viscosity; oxidation stability index; and acid number. The analyses were conducted immediately after opening the barrel, and again after two months of storage in a laboratory. The results were compared to those measured for the fresh fuel, seven years earlier. The comparison of the results indicate that the fuel quality had suffered no serious deterioration during the seven-year period.
